高盐有机废水处理技术研究新进展钟璟

CHEMICALINDUSTRYANDENGINEERINGPROGRESS2012314920213164/TQ028A10006613201204092007RecentdevelopmentsintreatmenttechnologyforhighlysalineorganicwastewaterZHONGJingHANGuangluCHENQunSchoolofPetrochemicalEngineeringChangzhouUniversityJiangsuProvincialKeyLaboratoryofFinePetrochemicalEngineeringChangzhou213164JiangsuChinaAbstractWiththedevelopmentofindustrytheincreasingdischargeofhighlysalineorganicwastewaterplaysadverseimpactsontheenvironment.Inthispapertheapplicationofconventionalphysico-chemicalmethodsespeciallymembraneseparationtechnologyforthetreatmentofhighlysalineorganicwastewaterissummarized.Thebiologicalmethodsincludingaerobicanaerobicandaerobic/anaerobichybridtechnologiesarealsowidelyusedindisposingofhighlysalineorganicwastewaterandtheperformanceofwhichdependsonthecultivationanddomesticationofhalophilicmicroorganisms.Thesynthesisofhigh-efficiencyoxidantspreparationofmembraneswithbettercostperformancerapidacclimatizationofhalophilicbacteriaanddevelopmentofnewreactorwouldbehotpointsintreatmentofhighlysalineorganicwastewaterandthecombinedtechnologyofphysico-chemicalmethodsandbiologicalmethodswouldbethefutureresearchorientationfortreatmentofhighlysalineorganicwastewater.Keywordshighlysalineorganicwastewaterphysico-chemicalmethodsbiologicalmethodscombinedtechnology[1][e-mail][e-mail]492111.18001000[2]COD40000mg/L5%COD150mg/L318/+422/390/[3]1.2[4][5]250mL2501000mg/L2450MHz800W28minBOD5/COD0.2[6]/[7]O3/H2O2O3H2O2[8]1.3Jorgensen[9]Dowex50w-x8PuroliteMN-500Choi[10]49.28mg/g201231922Tang[11]Elkady[12]1.4[13][14]BOD5/COD0.39[15]CODCOD4514mg/L1050mg/LCOD77%COD34.2%Sundarapandiyan[16]pHCODTKN0.024A/cm2pH91kgTKN1kgCOD22.45kWh0.80kWh1.51.5.1COD[17]PPESK[18]COD15000mg/LSO4217g/LCOD1800mg/LSO425g/L95%[19]-pHCODTOC80%94%Campos[20]CODTOC35%25%35%2mm12hCODTOC65%80%65%1.5.2[21]Mansoor[22]HS4923Covarrubias[23]FAULi[24]MFI2.75MPa95%1.5.3[25]100%[26]22%2.5kg/(m2?h)COD400mg/L80Mohammadi[27]TaguchimethodSafavi[28]Feng[29]2105m/sGryta[30]1.5.4Noworyta[31]Garc[32]Khajavi[33]99.99%0.1s/cm22.1201231924[34]YS-172hCOD90.0%120hCOD98.1%[35]5525pH18%30%[36]3pHBOD5CODpHBOD53%COD80%COD[37]Cl73g/LCOD3.9g/L3COD77%ClAbou-Elela[38]7.2%0.5%3%1%COD80%90%2%COD91%COD74%2.21965[39]SBBR02%COD300mg/L12h0.6L/min20003500mg/L18COD97%93%Aloui[40]COD[41][42]Artiga[43]COD7.811.8g1.21.8g/L84g/LCOD73COD93%Bassin[44]2.3[45]914g/L1722g/LCOD70%28g/LJeison[46]Vyrides[47]035g/L0.070105PaDOC30%72h49252.4/Lefebvre[48]-71g/LCOD78%COD96%[49]A/OCOD96%87.5%59.4%A/O3-[50]Fenton---COD5163g/L7591g/LGB89781996[51]++BOD5COD99.5%99.8%GB89781996DB37/65620064[1].[J].200827389-92.[2].[J].200832370-71.[3].101825285[P].2010-09-08.[4].[J].200417627-29.[5].101525177[P].2009-09-09.[6].102020350[P].2011-04-20.[7].O3/H2O2[J].20102961138-1142.[8].[J].20113081841-1847.[9]JorgensenTCWeatherlyLR.Ammoniaremovalfromwastewaterbyionexchangeinthepresenceoforganiccontaminants[J].WaterResearch2003371723-1728.[10]ChoiJae-WooLeeSeung-YeonParkKi-Youngetal.Investigationofphosphorousremovalfromwastewaterthroughionexchangeofmesostructurebasedoninorganicmaterial[J].Desalination2011266281-285.[11]TangXWLiZZChenYMetal.RemovalofZnfromaqueoussolutionwithnaturalChineseloessBehaviorsandaffectingfactors[J].Desalination200924949-57.[12]ElkadyMFAbu-SaiedMAAbdelRahmanAMetal.Nano-sulphonatedpolyglycidylmethacrylatecationsexchangerforcadmiumionsremovalEffectsofoperatingparameters[J].Desalination2011279152-162.[13].[J].200925121060-1063.[14].201231926[J].201029662-665.[15].[J].2010367104-107.[16]SundarapandiyanSChandrasekarRRamanaiahBetal.Electrochemicaloxidationandreuseoftannerysalinewastewater[J].JournalofHazardousMaterials2010180197-203.[17].[J].200822810-13.[18].[J].2008341172-74.[19].+[J].20102364-7.[20]CamposJCBorgesRMHOliveiraFilhoAMetal.Oilfieldwastewatertreatmentbycombinedmicrofiltrationandbiologicalprocesses[J].WaterResearch20023695-104.[21].101690869[P].2010-04-07.[22]MansoorK.Newnanoporezeolitemembranesforwatertreatment[J].Desalination2010251176-180.[23]CovarrubiasCGarcaRArriagadaRetal.RemovaloftrivalentchromiumcontaminantfromaqueousmediausingFAU-typezeolitemembranes[J].JournalofMembraneScience2008312163-173.[24]LiLXDongJHNenoffTM.TransportofwaterandalkalimetalionsthroughMFIzeolitemembranesduringreverseosmosis[J].SeparationandPurificationTechnology20075342-48.[25].[J].200424154-59.[26].[J].20114029-12.[27]MohammadiTSafaviMA.Applicationoftaguchimethodinoptimizationofdesalinationbyvacuummembranedistillation[J].Desalination200924983-89.[28]SafaviMMohammadiT.High-salinitywaterdesalinationusingVMD[J].ChemicalEngineeringJournal2009149191-195.[29]FengCYKhulbeKCTabeS.Volatileorganiccompoundremovalbymembranegasstrippingusingelectro-spunnanofibermembrane[J].Desalination201228798-102.[30]GrytaMTomaszewskaMKarakulskiK.Wastewatertreatmentbymembranedistillation[J].Desalination200619867-73.[31]NoworytaATrusek-HolowniaAMielczarskiSetal.Anintegratedpervaporation-biodegradationprocessofphenolicwastewatertreatment[J].Desalination2006198191-197.[32]Ga