炼油厂制氢技术路线选择_马文杰

225Vol.22No.520169CleanCoalTechnologySep．2016121．2016122．315203、、/、、。/0.74/m31.42/m30.87/m3。/。TQ116.2A1006－6772201605－0064－06SelectionofhydrogenproductiontechnologyforrefineryplantMAWenjie1YINXiaohui21．PanwenShanghaiAutomationEngineeringCo．Ltd．Shanghai201612China2．SinopecNingboEngineeringCo．Ltd．Ningbo315203ChinaAbstractInordertoselecteconomicalandeffectivehydrogenproductiontechnologyforrefineryplantinChinaandobtainhighqualityproducewithlowcostthetechnologicalprocessesinvestmentcostofsteammethanereformerSMＲheavyoilpoxcoal/petcokepoxcokeovengasCOGpoxwerecompared．Theresultsshowedthatthecoal/petcoketohydrogenhadthelowestcostofＲMB0．74percubicmetretheheavyoilpoxhadthehighestcostofＲMB1．42percubicmeterthecostofnaturalgastohydrogenＲMB0．87percu-bicmeterwhichwasstillhigherthanthecostofcoaltohydrogeneveninadownmarket．Thecoal/petcoketohydrogenprocesshadthecostadvantageanditalsocouldoptimizethematerialbalanceofrefinerywhichwasstillthemaindevelopingdirectionofcomplementinghydro-genindomesticrefinery．Keywordshydrogenproductionsteamreformingcoalgasificationhydrogenproductioncost2016－05－03DOI10．13226/j．issn．1006－6772．2016．05．0121973—、。[e-mail]201622564－69．0、。、、、、、、。。。、、、1－2。3、399.9999%、、、。、。2。4、52。246201656－7。。。12。、。。95%。、“”。。201622511《》“”20161111V、201711V、。2、。1。22。①。。4%、PSA。。②。、。2。1Table1Hydrogenbalanceoftypicalrefineryplantt/a10.3613.447.971.233.193.842.688.1314.287.50PSA2.4520.9432.1421.996.5912.898.789.820.553.453.743.270.375.528.670.591.370.250.020.850.06PX1.68PSA4.462.1420.9432.1421.992Table2Hydrogensourceofsomerefineryplants/m3·h－1、10201510920144、18.82014162014162009919842009、3.520081032008、13.720059。、、562016522、/、。。33.13.1.1、、CO、PSA81。1Fig.1Processofnaturalgastohydrogen3.1.2、、CO、PSA2。2Fig.2Processofrefinerydrygastohydrogen3.1.3、、CO、PSA3。3Fig.3Processofnaphthatohydrogen3.2、。、、、、PSA94。4Fig.4Processofheavyoiltohydrogen3.3/、、、、、。、、、。。、3CH4CO+H210。26620165。、、、。、。/、、、、PSA5。5/Fig.5Processofcoal/petcoketohydrogen3.4H2、CH4C2、C3CO2、N2、、H2S、、。、H2CO、、。。、、、、CO、PSA6。44.110m3/h8000h＞99.9%CO+CO2＜20×10－6。201552.41/3。6Fig.6Processofcokeovengastohydrogen3Table3Priceofrawmaterial2.11/m3410/t2.86/m3250/t2917/t1.11/m3DOA2000/t1750/t2500/t4.24。、。4E2.48E。。、、。。4.327。7、。1.23/m3110/t0.52/m37620165224Table4Comprehensivetechnicalindex/m3·h－138730/m3·h－137116/t·h－126.5/t·h－137.9/t·h－13.0/t·h－169.9/t·h－12.2/m3·h－17969210.0MPa/t·h－12054.0MPa/t·h－185.393.9122.834.0127.0110.01.0MPa/t·h－110.0/t·h－1639.0612.41420.017423.015147.010810.0/kW7450.06520.03310.07332.010304.01978.0/t·h－1150.4157.3212.3145.5/m3·h－15531.1/kg·h－132.032.0/t·h－1122.0H2/m3·h－110000010000010000010000010000010000010.0MPa/t·h－156.05.8MPa/t·h－1126.3143.0193.00.5MPa/t·h－116.716.0/t·h－142.745.466.283.068.5132.0/GJ·h－1274.23559.45341.868/m3·h－143111000m3/GJ12.54113.05111.54020.33423.69216.664EE1.02E1.07E1.99E2.48E1.46E/·m－30.871.100.921.420.740.96/·m－30.861.090.911.410.730.95H299.9%。7Fig.7Hydrogencostcomparisonbetweennaturalgasandcoaltohydrogen1.23/m32.11/m30.86/m3600/t。5、。。。。/8620165。Ｒeferences1．J．20032854－9．LiuShaowenWuGuangyi．ＲeviewonproductionofhydrogenJ．GuizhouChemicalIndustry20032854－9．2．J．200523936－40．ChuHonglingWangGuizhiGongFanetal．Discussionofhydro-genprocesstechnologiesJ．ChemicalTechno－Economics200523936－40．3．J．200724372－74．LiuYiming．Comparisonandselectionofprocessofhydrogenpro-ductionJ．Chemistry＆Bioergineering200724372－74．4．J．200925360－62．YinZhonghui．Economiccomparisonofhydrogenmanufacturetech-nologybetweencoalgasificationandnaturalgassteamreformationJ．Technology＆EconomicsinPetrochemicals200925360－62．5．J．C1201540178－82．LiQingxunLiuXiaotongLiuKefengetal．Technicalandeconom-icanalysisforlarge－scaleindustrialhydrogenproductionJ．Natu-ralGasChemicalIndustry201540178－82．6．J．201434554－56．ZhangPeilanZhengLi．Severalindustryhydrogenproductiontech-nologyandeconomicanalysisJ．ShanxiChemicalIndustry201434554－56．7．J．20103810141－145．ZhangWei．SelectionofrouteforhydrogenproductioninrefineryanditscostanalysisJ．ChemicalEngineering20103810141－145．8．J．20024038－13．9．ⅢJ．20073831－4．ShiYahuaLiJiadongDaiLishun．StudyonresidueprocessingtechnologyIIIprocessingschemeandeconomicbenefitJ．PetrolumProcessingandPetrochemicals20073831－4．10．M．2003329－655．檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶檶63HuangZhongJiangJianzhongXuZhengquanetal．ＲesearchonCFBboilerlargeproportioncoalslimeco－combustiontestJ．Pro-ceedingsoftheChineseSocietyforElectricalEngineering201333S1112－116．5．M．2．20085－9．6．CFBJ．2015215103－106．WeiＲongzhangBaiTao．SelectionofslagconveyingsystemofCFBboilerJ．CleanCoalTechnology2015215103－106．7．J．201437455－57．ZhuHonglongZhangChuanxiangMaMingjieetal．ExperimentalstudyoncombustioncharacteristicsofcoalslimebriquetteJ．CoalConversion201437455－57．8．CFBJ．2015341327－330．LiLifengZhangYiZhangPeihuaetal．CFBboilerblendcombus-tioncoalslurrybriquettefordeepdesulfurizationandresearchonoperatingcharacteristicsJ．CoalTechnology2015341327－330．9．J．201521499－102．YuanJian．Ｒesearchprogressofcoaldesulfurizat