物料安全数据表（英文版）

MATERIALSAFETYDATASHEETGasoline,PremiumUnleadedMSDSNo.0324RevisionDate:12/30/97Page1of81.CHEMICALPRODUCTandCOMPANYINFORMATION(rev.Dec-97)AmeradaHessCorporation1HessPlazaWoodbridge,NJ07095-0961EMERGENCYTELEPHONENUMBER(24hrs):CHEMTREC(800)424-9300COMPANYCONTACT(businesshours):CorporateSafety(732)750-6000SYNONYMS:93OctaneConventional(OxygenatedandNon-oxygenated)andReformulated(RFG)PremiumUnleadedGasolineSeeSection16forabbreviationsandacronyms.2.COMPOSITIONandINFORMATIONONINGREDIENTS*(rev.Dec-97)INGREDIENTNAME*EXPOSURELIMITSCONCENTRATIONPERCENTBYWEIGHTGasolineCASNUMBER:8006-61-9OSHAPEL-TWA/STEL:NoneestablishedACGIHTLV-TWA/STEL:300/500ppm,A3100BenzeneCASNUMBER:71-43-2OSHAPEL-TWA/STEL:1/5ppmACGIHTLV-TWA:0.5/2.5ppm,A1,skinUSCoastGuard:sameasOSHA0.1to4.90.1to1.3**forreformulatedgasolineMethyl-tertiarybutylether(MTBE)CASNUMBER:1634-04-4OSHAPEL-TWA/STEL:NoneestablishedACGIHTLV-TWA:40ppm,A30to15.0Tertiary-amylmethylether(TAME)CASNUMBER:994-05-8Noneestablished0to17.2TolueneCASNUMBER:108-88-3OSHAPEL-TWA/Ceiling:200/300ppmOSHAPEL-Peak:500ppm(10min.)ACGIHTLV-TWA:50ppm,A4(skin)1-25Xylene,mixedisomersCASNUMBER:1330-20-7OSHAPEL-TWA:100ppmACGIHTLV-TWA/STEL:100/150ppm,A41-15Acomplexblendofpetroleum-derivednormalandbranched-chainalkane,cycloalkane,alkene,andaromatichydrocarbons.Butaneisoftenaddedtoincreasevolatility,especiallyinwinter.Maycontainantioxidantandmultifunctionaladditives.Oxygenatedandreformulatedgasolinewillhavelegally-requiredamountsofoxygenates(MTBEand/orTAME).*AlsoseeSection15forlistofSARASection313toxicchemicalsandtheirexposurelimits.3.HAZARDSIDENTIFICATION(rev.Dec-97;Tox-97)EMERGENCYOVERVIEWDANGER!EXTREMELYFLAMMABLE-EYEANDMUCOUSMEMBRANEIRRITANT-EFFECTSCENTRALNERVOUSSYSTEM-HARMFULORFATALIFSWALLOWED-ASPIRATIONHAZARDHighfirehazard.Keepawayfromheat,spark,openflame,andotherignitionsources.Ifingested,doNOTinducevomiting,asthismaycausechemicalpneumonia(fluidinthelungs).Contactmaycauseeye,skinandmucousmembraneirritation.Harmfulifabsorbedthroughtheskin.Avoidprolongedbreathingofvaporsormists.Inhalationmaycauseirritation,anestheticeffects(dizziness,nausea,headache,intoxication),andrespiratorysystemeffects.Long-termexposuremaycauseeffectstospecificorgans,suchastotheliver,kidneys,blood,nervoussystem,andskin.Containsbenzene,whichcancauseblooddisease,includinganemiaandleukemia.NFPA704(Section16)MATERIALSAFETYDATASHEETGasoline,PremiumUnleadedMSDSNo.0324RevisionDate:12/30/97Page2of8EYESModerateirritant.Contactwithliquidorvapormaycauseirritation.SKINModerateirritant.Maycauseskinirritationwithprolongedorrepeatedcontact.Practicallynon-toxicifabsorbedfollowingacute(single)exposure.Liquidmaybeabsorbedthroughtheskinintoxicamountsiflargeareasofskinareexposedrepeatedly.INGESTIONThemajorhealththreatofingestionoccursfromthedangerofaspiration(breathing)ofliquiddropsintothelungs,particularlyfromvomiting.Aspirationmayresultinchemicalpneumonia(fluidinthelungs),severelungdamage,respiratoryfailureandevendeath.Ingestionmaycausegastrointestinaldisturbances,includingirritation,nausea,vomitinganddiarrhea,andcentralnervoussystem(brain)effectssimilartoalcoholintoxication.Inseverecases,tremors,convulsions,lossofconsciousness,coma,respiratoryarrest,anddeathmayoccur.INHALATIONExcessiveexposuremaycauseirritationstothenose,throat,lungsandrespiratorytract.Centralnervoussystem(brain)effectsmayincludeheadache,dizziness,lossofbalanceandcoordination,unconsciousness,coma,respiratoryfailure,anddeath.WARNING:theburningofanyhydrocarbonasafuelinanareawithoutadequateventilationmayresultinhazardouslevelsofcombustionproducts,includingcarbonmonoxide,andinadequateoxygenlevels,whichmaycauseunconsciousness,suffocation,anddeath.CHRONICEFFECTSandCARCINOGENICITYContainsbenzene,aregulatedhumancarcinogen.Benzenehasthepotentialtocauseanemiaandotherblooddiseases,includingleukemia,afterrepeatedandprolongedexposure.Exposuretolighthydrocarbonsinthesameboilingrangeasthisproducthasbeenassociatedinanimalstudieswithsystemictoxicity.SeealsoSection11-ToxicologicalInformation.MEDICALCONDITIONSAGGRAVATEDBYEXPOSUREIrritationfromskinexposuremayaggravateexistingopenwounds,skindisorders,anddermatitis(rash).Chronicrespiratorydisease,liverorkidneydysfunction,orpre-existingcentralnervoussystemdisordersmaybeaggravatedbyexposure.4.FIRSTAIDMEASURES(rev.Dec-97;Tox-97)EYESIncaseofcontactwitheyes,immediatelyflushwithclean,low-pressurewaterforatleast15min.Holdeyelidsopentoensureadequateflushing.Seekmedicalattention.SKINRemovecontaminatedclothing.Washcontaminatedareasthoroughlywithsoapandwaterorwaterlesshandcleanser.Obtainmedicalattentionifirritationorrednessdevelops.INGESTIONDONOTINDUCEVOMITING.Donotgiveliquids.Obtainimmediatemedicalattention.Ifspontaneousvomitingoccurs,leanvictimforwardtoreducetheriskofaspiration.Smallamountsofmaterialwhichenterthemouthshouldberinsedoutuntilthetasteisdissipated.INHALATIONRemovepersontofreshair.Ifpersonisnotbreathing,ensureanopenairwayandprovideartificialrespiration.Ifnecessary,provideadditionaloxygenoncebreathingisrestorediftrainedtodoso.Seekmedicalattentionimmediatel